Concerning the Efficiency of Corrosion Inhibitors as Given by SVET

نویسندگان

  • A. C. Bastos
  • M. L. Zheludkevich
  • M.G.S. Ferreira
چکیده

The possibility of obtaining corrosion inhibition efficiency from the Scanning Vibrating Electrode Technique (SVET) is investigated. Results are compared with those obtained by Electrochemical Impedance Spectroscopy (EIS) for the inhibition of iron and zinc with cerium nitrate and 1H-benzotriazole. Examples of good and bad estimations are given and an interpretation for the discrepancies observed is advanced. Large deviations occur when corrosion products are formed since this leads to an underestimation of the currents measured by SVET. Visual inspection of the samples may identify the cases more susceptible to deviation. The approach discussed here can be used to obtain more quantitative information from SVET measurements but should not replace the traditional ways used to determine the inhibition efficiency.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Effect of Alkyl Chain Length on Adsorption Behavior and Corrosion Inhibition of Imidazoline Inhibitors

Inhibition performances of imidazoline derivatives with different alkyl chain length for carbon steel in H2S acid solutions has been studied by polarization curves, AC impedance measurements, current transient, Atomic Force Microscopy (AFM) and Density Functional Theory (DFT) techniques. Results showed that the inhibition occurs through adsorption of the inhibitors molecules ...

متن کامل

Theoretical study for evaluation of corrosion inhibition performance of two thiocarbohydrazide inhibitors

Molecular dynamics (MD) simulation and Density functional theory (DFT) methods were applied to the two thiocarbohydrazides derivatives (T1 and T2) as corrosion inhibitors for carbon steel in aqueous phase. Experimental results have shown that the corrosion rate follows the below order: T1>T2. Quantum chemical parameters such as hardness (η), electrophilicity (ω),polarizability (α), dipole momen...

متن کامل

Electrochemical assessment of imidazole derivatives as corrosion inhibitors for mild steel in 3.5 NaCl solution

The corrosion inhibition efficiency of benzimidazole, 2-methylbenzimidazole and 2- aminobenzimidazole for mild steel immersed in 3.5 NaCl solution was investigated by electrochemical impedance spectroscopy EIS at concentration range from 10-5 to 10-2 M of imidazoles and temperature range from 30 to 50°C. In addition, DC polarization was examined to determine inhibition mechanism at concentratio...

متن کامل

Talinum triangulare leaf and Musa sapientum peel extracts as corrosion inhibitors on ZA-27 Alloy

With the current emergence of green chemistry to keep the environment safe, attention is being shifted towards using plant extracts as corrosion inhibitors. The inhibitive performances of Talinum triangulare leaf extract and Musa sapientum peel extract on the ZA-27 in 1.0 M and 1.5 M hydrochloric acid solutions were studied for 18 days using mass loss measurement. The corrosion inhibition effic...

متن کامل

SYNERGISTIC INFLUENCE OF NITRITE ON INHIBITION OF MILD STEEL CORROSION IN CHLORIDE CONTAMINATED ALKALINE SOLUTION

Corrosion behavior of mild steel in chloride contaminated alkaline solution has been studied for the period up to 100days. Saturated Calcium hydroxide solution was used as alkaline solution and 0.5M NaCl solution was used to accelerate mild steel corrosion. The Charge transfer resistance Rct, Current density Icorr and inhibition efficiency values were obtained from tafel polarization and electr...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2008